Mark, I spent nearly 10 years in retail glass and we did a lot of new installs, as well as replacement for shower cubicles, so came upon many instances of this type of breakage. You didn't mention if it was one panel of several, framed or frameless, or how long it has been used prior to the incident, which can have a bearing on the best option, but will try to cover a few scenarios . . .
Without a doubt toughened should be your best bet. Never even seen a toughened panel breakage in a cubicle. It just shouldn't break with thermal shock of hot water hitting cold glass etc, and unless the edges are exposed (the weakest point) it should withstand quite strong hammer blows ! One reason I'm not a big fan of frameless doors is that a fairly moderate hit on the edge with a hard object can cause toughened to break. A very sharp impact can break toughened, eg we did lots of patio sliding door replacements over the years after someone had mowed the grass. Likely scenario is a small stone was flung and hit the glass, sometimes they explode much later in the day when temp changes caused thermal contraction or expansion.
As Chris said, it was most likely a manufacturing defect . . . but how long was it in situ before the incident ?
Laminated will be mildly safer, as the interlayer will hold the glass together quite well. It is commonly used in cheaper versions of cubicles in either 5.38mm or 6.38 thickness, but is weaker re impact, and hot water on cold glass will sometimes cause thermal breakage, but not quite as easy as the older out of date wired glasses. Bear in mind, with lam there would very likely still be some small splinters come from the break line (spalling).
Lexan (5mm or 6mm) could be your best option, it is tough, even moreso than toughened glass for impact, and should present no issues with safety. Just a cleaning / appearance issue over time, but that is minor compared to the other option. Some things to consider. Are there other panels you would need to change also ? Lexan is very expensive compared to any of the glasses mentioned above.